Rapid aerobic iodination of arenes mediated by hypervalent iodine in flourinated solvents

Author(s)
Murphree, S. Shaun
Iskra, Jernej
Date Issued
January 4, 2017
Abstract
Arenes are rapidly converted to the corresponding iodides by aerobic oxidative iodination at room temperature by treatment with iodine and catalytic quantities of nitrous acid in a fluorinated solvent. Dichloroiodic acid is proposed as the actual iodination reagent.
Journal
Tetrahedron Letters
Department
Biochemistry
Chemistry
Citation
Iskra, J., and Murphree, S.S. (2017). Rapid aerobic iodination of arenes mediated by hypervalent iodine in flourinated solvents. Tetrahedron Letters 58: 645-648. doi:10.1016/j.tetlet.2017.01.003
Publisher
Elsevier
Version of Article
Published article
DOI
10.1016/j.tetlet.2017.01.003
ISSN
0040-4039
Rights
Published version is restricted by copyright. Please contact author or publisher for access.
Subjects

Aromatic substitution...

Hypervalent compounds...

Iodination

Fluorinated solvents

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