Rapid aerobic iodination of arenes mediated by hypervalent iodine in flourinated solvents

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2017-01-04
Authors
Murphree, S. Shaun
Iskra, Jernej
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Murphree_2017_TetrahedronLetters_iodination.pdf (2.06 MB)
Murphree_2017_Tetrahedron_iodination_cover.pdf (327.42 KB)
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http://hdl.handle.net/10456/42590
Keywords
Aromatic substitution , Hypervalent compounds , Iodination , Fluorinated solvents
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Abstract
Arenes are rapidly converted to the corresponding iodides by aerobic oxidative iodination at room temperature by treatment with iodine and catalytic quantities of nitrous acid in a fluorinated solvent. Dichloroiodic acid is proposed as the actual iodination reagent.
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Biochemistry
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Iskra, J., and Murphree, S.S. (2017). Rapid aerobic iodination of arenes mediated by hypervalent iodine in flourinated solvents. Tetrahedron Letters 58: 645-648. doi:10.1016/j.tetlet.2017.01.003
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Published article
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Elsevier
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